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Topchiev/ Radiolysis of Hydrocarbons

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Topchiev , A.V.
Radiolysis of Hydrocarbons [#547ar32]

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Published by Norwood Elsevier Publishing Company, London, 1964; xii + 232 pages, including graphs, tables formulae, equations, references and subject Index; 17 X 25cm; "Good+" sky blue/gilt cloth hardback; formerly the property of the City Of Liverpool Public Libraries, with their neat ownership and 'withdrawn' stamps on top and bottom of closed page edges; evidence still of librarian's use of transparent tape, remains of lending or reference sheet on front flyleaf. *** "The appearance of this edition of A. V. Topchiev's book will be welcomed by radiation chemists as one of the few comprehensive reviews of radiation chemistry in the USSR to be published in English. Although it is basically a description of research activities carried out in the years 1957-1961 at the Radiation Research Laboratories of the Institute for Petrochemical Synthesis and covers such diverse subjects as thermal cracking and energy transfer, the book remains coherent and unified throughout, largely because of the underlying objective, which was to elucidate the mechanism of the radlolysis of saturated hydrocarbons in both the liquid and solid phases. A topic of particular interest discussed at length is that of energy transfer In binary systems. This phenomenon is demonstrated by electron spin resonance measurements which have shown that inhibitors such as benzene reduce the radical yield in irradiated solid hydrocarbons. A very detailed analysis of the effect of various inhibitors on the yields of all the products of irradiated hydrocarbons, such as hexane in the liquid phase, leads the author to postulate that excitation energy is removed by the inhibitor before transfer of energy to vibrational levels occurs. A general theory is derived, based on the assumption that inhibition occurs by a radiatlonless electromagnetic transition, and is shown to correctly predict the observed concentration dependence of the effect. There is a wealth of experimental data presented, and this is interpreted In terms of mathematical correlations and theoretical considerations. A full quarter of the book is devoted to the statistical theory of activation processes in condensed phases. This theory Is derived for thermal activation and then is applied to the specific case of activation initiated by ionizing radiation." *** A decent crisp/clean copy of infrequently encountered item.




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This page was freshly revised & updated on Tuesday 14th. May 2013..

Anybody see the BBC 4 prog. last week on arthropods ? 'More big words to follow. Spot the glaring 'deliberate mistake' ? Most of you can drift off to another blog now; here comes the boring ex-biology teacher bit. The voice-over 'droned' on (very bad pun that I couldn't resist) about how we couldn't possibly get enough food without bees then, by way of illustration, we were treated to a shot of acres of wheat. Wheat, of course, is anemophilous. If you don't know what that means, you should have been listening in the biol. class.

I'm presuming here that our friends 'isolated' on the mainland do watch some of our TV. Little doth it profit them. However, my experience of German TV is that it is worse than ours. Hardly possible, you'd think.

No matter how many books we pull out of the reserve stock on the top floor it never lessens. Forget the big bang or continuous creationthe material universe comes into being in our store room, as discrete self-informative bits, as books. David Icke started with dafter ideas than that --- perhaps

A few days ago the family watched -- comforted by lots of tea and big sticks of sweet liquorice -- a promising programme on Pompeii and Herculaneum. The Radio Times magazine hadn't marked it as a "repeat." Now here's the cheat: within the whole bloody hour-long bore the same half-dozen already familiar facts were repeated ad nauseam. True, the presenter was filmed walking amongst the same objects but in varying directions and we were treated to a whole Roget's Thesaurus of pointless synonyms. Do you really need a Ph.D. or professorial chair to present such reception class drivel?

Two days ago we watched -- expecting something better -- the Worsthorne prog. on the royals and their medical problems. We should have noticed the crap was coming in the first five minute: "heading off" instead of "going"/ "I'm going to explain why"/ "explore"/"secrets of" and so on. Then we get the 'Hammer Horror Films' tudors. Professors from leading universities get their few quid from the BBC to tell us what we know already. No real medical stuff at all. Not a word about fat Henry's gammy leg, his paranoia and possible syphilis. Bloody Mary gets the usual stuff and on the almost equally bloody Elizabeth we get the usual whitewash job. No nuanced history, as ever. History on the telly -- from the Beeb even -- tends to be simplistic garbage. I'm giving it up -- except for Lent!

The language section is now heaped up with oodles of foreign language versions of English novels. Theology is overflowing with evangelical paperbacks. Bargain books -- at 50p or 5 for 2 -- are falling off the shelves in the yard -- even blowing off in the recent winds.

This site is well worth your time.

All lancastrians will find it delightful.

I'm told the site is doing well. Lancastrian expatriates are visiting in fair numbers.

I've been told also that Gerard Swarbrick invented Appledore cheese. Is that so? You can now buy it at Grandma Singleton's cheese shop just by Preston market. ... Taken From Today's Home Page Jottings.

If you are within 30 miles of the shop, switch that machine off and come and see us.
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