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Browse Our Catalogues Plesek and Hermanek / Sodium Hydride Its Use In the Laboratory and in Technology

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Published by Iliffe Books Ltd, London, 1968; 185 pages, including tables, bond structures, formulae, references  and subject index; 17.5 X 25cm; "Very Good+" brown/marble effect/gilt cloth hardback with library  ownership stamp on verso of title page and small 5-digit stamp on  front flyleaf. ***  "Sodium hydride has been known since the year 1878. As a  chemical, however, it appeared for the first time on the market  as late as about 1937. This substance, originally interesting  from the viewpoint of theoretical chemistry only, has become,  within a relatively short time, a basic chemical of a new field  the chemistry of complex hydrides. Of considerable technological  significance also was the discovery that sodium hydride is highly  effective in the deoxidation of metal surfaces and in this  respect affords one of the most economic procedures. The application of sodium hydride in organic chemistry is highly  promising. Although already several hundred successful  applications in this field have been published, sodium hydride  continues to be a substance almost unknown to chemists. Mentions  of its use are so widely scattered in the literature that it is  difficult to find them. Even the entry sodium hydride is referred  to in the abstract literature only if the entire paper is  concerned with this agent. This may be just the reason why sodium  hydride has so far been regarded by organic chemists as a mere  laboratory curiosity without great significance, although a  number of findings were summarized in the reports of Hansley and Banus, as well as in publications of manufacturers. The  outstanding properties of sodium hydride were not recognized  immediately. Different opinions as to its efficiency were  influenced by the quality of the hydride available to individual  experimenters. In particular, the sodium hydride employed at the  beginning of the fifties was often relatively coarse-grained and  of poor chemical purity and reactivity. Since that time, there  have appeared not only uniform fine dispersions of sodium hydride  in liquid paraffin, but also a dry pulverous hydride with an  extraordinarily large specific surface, either of which is  considerably more effective. At present, it is beyond any doubt  that sodium hydride has become one of the most useful agents,  converting even extremely weak acids into salts, which permits  not only their subsequent alkylation or acylation, but also the  condensation of substances with activated hydrogen on carbon with  most diverse types of carbonyl compounds." *** A decent crisp/clean copy of a scarce item.


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