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Plesek and Hermanek / Sodium Hydride Its Use In the Laboratory and in Technology£45 or $70 or 54 Euros Postfree-By-Airmail Worldwide
Published by Iliffe Books Ltd, London, 1968;
185 pages, including tables, bond structures,
formulae, references
and subject index; 17.5 X 25cm;
"Very Good+" brown/marble effect/gilt cloth
hardback with library
ownership stamp on verso of title page and small
5-digit stamp on
front flyleaf. ***
"Sodium hydride has been known since the year
1878. As a
chemical, however, it appeared for the first time
on the market
as late as about 1937. This substance, originally
interesting
from the viewpoint of theoretical chemistry only,
has become,
within a relatively short time, a basic chemical
of a new field
the chemistry of complex hydrides. Of
considerable technological
significance also was the discovery that sodium
hydride is highly
effective in the deoxidation of metal surfaces
and in this
respect affords one of the most economic
procedures.
The application of sodium hydride in organic
chemistry is highly
promising. Although already several hundred
successful
applications in this field have been published,
sodium hydride
continues to be a substance almost unknown to
chemists. Mentions
of its use are so widely scattered in the
literature that it is
difficult to find them. Even the entry sodium
hydride is referred
to in the abstract literature only if the entire
paper is
concerned with this agent. This may be just the
reason why sodium
hydride has so far been regarded by organic
chemists as a mere
laboratory curiosity without great significance,
although a
number of findings were summarized in the reports
of Hansley
and Banus, as well as in publications of
manufacturers. The
outstanding properties of sodium hydride were not
recognized
immediately. Different opinions as to its
efficiency were
influenced by the quality of the hydride
available to individual
experimenters. In particular, the sodium hydride
employed at the
beginning of the fifties was often relatively
coarse-grained and
of poor chemical purity and reactivity. Since
that time, there
have appeared not only uniform fine dispersions
of sodium hydride
in liquid paraffin, but also a dry pulverous
hydride with an
extraordinarily large specific surface, either of
which is
considerably more effective. At present, it is
beyond any doubt
that sodium hydride has become one of the most
useful agents,
converting even extremely weak acids into salts,
which permits
not only their subsequent alkylation or
acylation, but also the
condensation of substances with activated
hydrogen on carbon with
most diverse types of carbonyl compounds."
*** A decent crisp/clean copy of a scarce item.
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